Distinct nonequilibrium plasma chemistry of C2 affecting the synthesis of nanodiamond thin films from C2H2 (1%)/H2/Ar-rich plasmas

6 pages, 5 figures, 6 tables.We show that the concentrations of the species C2 (X 1Σg+), C2 (a 3Πu), and C2H exhibit a significant increase when the argon content grows up to 95% in medium pressure (0.75 Torr) radio frequency (rf) (13.56 MHz) produced C2H2 (1%)/H2/Ar plasmas of interest for the synthesis of nanodiamond thin films within plasma enhanced chemical vapor deposition devices. In contrast, the concentrations of CH3 and C2H2 remain practically constant. The latter results have been obtained with an improved quasianalytic space–time-averaged kinetic model that, in addition, has allowed us to identify and quantify the relative importance of the different underlying mechanisms driving the nonequilibrium plasma chemistry of C2. The results presented here are in agreement with recent experimental results from rf CH4/H2/Ar-rich plasmas and suggest that the growth of nanodiamond thin films from hydrocarbon/Ar-rich plasmas is very sensitive to the contribution of C2 and C2H species from the plasma.This work was partially funded by CICYT (Spain) under a Ramón y Cajal project and under Project No. TIC2002- 03235. One of the authors (F.J.G.V.) acknowledges a Ramón y Cajal contract from the Spanish Ministry of Science and Technology (MCYT). One of the authors (J.M.A.) acknowledges partial support from CICYT (Spain) under Project No. MAT 2002-04085-C02-02.Peer reviewe

Nanoscopic surface inspection by analyzing the linear polarization degree of the scattered light

We present an optical method for the nanoscopic inspection of surfaces. The method is based on the spectral and polarization analysis of the light scattered by a probe nanoparticle close to the inspected surface. We explore the sensitivity to changes either in the probe–surface distance or in the refractive index of the surface

Extended discrete dipole approximation and its application to bianisotropic media

In this research we introduce the formalism of the extension of the discrete dipole approximation to a more general range of tensorial relative permittivity and permeability. Its performance is tested in the domain of applicability of other methods for the case of composite materials (nanoshells). Then, some early results on bianisotropic nanoparticles are presented, to show the potential of the Extended Discrete Dipole Approximation (E-DDA) as a new tool for calculating the interaction of light with bianisotropic scatterers

Roughening kinetics of chemical vapor deposited copper films on Si(100)

3 pages, 3 figures.The roughening kinetics of copper films synthesized by low pressure chemical vapor deposition (LPCVD) on Si(100) substrates was investigated by scanning tunneling microscopy (STM). By applying the dynamic scaling theory to the STM images, a steady growth roughness exponent (alfa)=0.81 ± 0.05 and a dynamic growth roughness exponent (beta)=0.62 ± 0.09 were determined. The value of (alfa) is consistent with growth model predictions incorporating surface diffusion. The value of (beta), while higher than expected from these models, can be related to LPCVD processing conditions favoring growth instabilities.This work was partially supported by the CSICCONICET cooperation program and by a grant from the NASA New Jersey Space Grant Consortium.Peer reviewe

Pembuatan Peta Zona Nilai Ekonomi Kawasan (Znek) Menggunakan Tcm (Travel Cost Method) Dan Cvm (Contingent Valuation Method) Berbasis Sistem Informasi Geografis (Studi Kasus : Candi Prambanan)

Prambanan Temple has potential as a tourist attraction. The strategic location which have historical value, makes this Place became one tourist destination areas Klaten. Based on this, we need a Zone Map Economic Value Areas (ZNEK) to the Prambanan area of the palace to estimate the economic value and benefits based on willingness to pay (WTP) tourists and the people who benefit from the region. Sampling method (respondents) were used in this research is non probability sampling with accidental sampling technique, where respondents are those who by chance / accidental encountered in the study area and can be used as a sample, if it is considered that the person who happened to be found suitable as a data source. Data processing method used is multiple linear regression analysis and calculation software WTP using Maple 17.Results obtained from the study of this final project is the Economic Value Area Zone maps with the total value of economic attraction Prambanan Temple Rp.32.851.020.029.000,- Maps generated from the integration of economic and spatial aspects can be used as an objective consideration of the decision-making process in the spatial field and economic field for the government to optimize and simplify the process of the asset\u27s management and monitoring the natural resources potential. Besides being able to provide a solution for the management of resource constraints of the economy in various regions in Indonesia, the map can be used too as a learning tool for the public society to bring awareness of the importance of potential belonging

Impact of the interfacial thermal conductance on the thermoplasmonic response of metal/polymer hybrid nanoparticles under nanosecond pulsed illumination

Janus nanoparticles containing plasmonic materials have attracted great attention in the thermoplasmonic community due to their potential for applications in thermoelectronics or biomedicine. A significant number of thermoplasmonic applications rely on the heating of nanostructures by using pulsed excitation lasers. The heating generated in these nanostructures is often transferred to other regions via material–fluid interfaces. This heat transfer dynamics is controlled by the interfacial thermal conductance. In this work, we investigate the impact of the interfacial thermal conductance on the thermal relaxation of metal–polymer Janus nanoparticles that generate directional heating under pulsed illumination. We show that neglecting the temperature dependence of the thermophysical properties results in an overestimation of the temperature of the nanoparticle. A gold/polymer semishell nanostructure was used as an example not only to illustrate the aforementioned effects but also to show it as a reliable nanoheater candidate for photothermal therapies, capable of offering a remarkable temperature increment and presenting directional heating. The model we developed here can be applied to any type of nanoarquitecture, showing this work as a powerful tool for topics beyond photothermal therapies that can contribute to the development of novel structures able to control heat on the nanoscale

Plasmonic nickel nanoantennas

7 páginas, 6 figuras.-- El pdf del artículo es la versión post-print.-- et al.The fundamental optical properties of pure nickel nanostructures are studied by far-field extinction spectroscopy and optical near-field microscopy, providing direct experimental evidence of the existence of particle plasmon resonances predicted by theory. Experimental and calculated near-field maps allow for unambiguous identification of dipolar plasmon modes. By comparing calculated near-field and far-field spectra, dramatic shifts are found between the near-field and far-field plasmon resonances, which are much stronger than in gold nanoantennas. Based on a simple damped harmonic oscillator model to describe plasmonic resonances, it is possible to explain these shifts as due to plasmon damping.Supported by the European FP7 project ‘Nanoantenna’ (FP7-HEALTH-F5-2009-241818-NANOANTENNA) and the National Project MAT2009 –08398 from the Spanish Ministerio de Ciencia e Innovacion. J.A. acknowledges fi nancial help by the Department of Industry of the Basque Government through the ETORTEK program NANOPHOT. P.V. acknowledges funding from the Basque Government under Programs No. PI2009–17 as well as the Spanish Ministry of Science and Education under Project No. MAT2009–07980. Z. P. acknowledges support from Swedish Foundation for Strategic Research through RMA08–0109 “Functional Electromagnetic Metamaterials” program. J. N. acknowledges funding from the Generalitat de Catalunya and the Spanish Ministry of Science and Education through No. 2009-SGR-1292 and No. MAT2010–20616-C02 projects. A.D. acknowledges support from the Swedish Research Council.Peer reviewe

Janus-Nanojet as an efficient asymmetric photothermal source

The combination of materials with radically different physical properties in the same nanostructure gives rise to the so-called Janus effects, allowing phenomena of a contrasting nature to occur in the same architecture. Interesting advantages can be taken from a thermal Janus effect for photoinduced hyperthermia cancer therapies. Such therapies have limitations associated to the heating control in terms of temperature stability and energy management. Single-material plasmonic nanoheaters have been widely used for cancer therapies, however, they are highly homogeneous sources that heat the surrounding biological medium isotropically, thus equally affecting cancerous and healthy cells. Here, we propose a prototype of a Janus-Nanojet heating unit based on toroidal shaped plasmonic nanoparticles able to efficiently generate and release local heat directionally under typical unpolarized illumination. Based on thermoplasmonic numerical calculations, we demonstrate that these Janus-based nanoheaters possess superior photothermal conversion features (up to ΔT≈35 K) and unique directional heating capacity, being able to channel up over 90% of the total thermal energy onto a target. We discuss the relevance of these innovative nanoheaters in thermoplasmonics, and hyperthermia cancer therapies, which motivate the development of fabrication techniques for nanomaterials

Marine Strategy Framework Directive - Task Group 3 Report - Commercially exploited fish and shellfish

The Marine Strategy Framework Directive (2008/56/EC) (MSFD) requires that the European Commission (by 15 July 2010) should lay down criteria and methodological standards to allow consistency in approach in evaluating the extent to which Good Environmental Status (GES) is being achieved. ICES and JRC were contracted to provide scientific support for the Commission in meeting this obligation. A total of 10 reports have been prepared relating to the descriptors of GES listed in Annex I of the Directive. Eight reports have been prepared by groups of independent experts coordinated by JRC and ICES in response to this contract. In addition, reports for two descriptors (Contaminants in fish and other seafood and Marine Litter) were written by expert groups coordinated by DG SANCO and IFREMER respectively. A Task Group was established for each of the qualitative Descriptors. Each Task Group consisted of selected experts providing experience related to the four marine regions (the Baltic Sea, the Northeast Atlantic, the Mediterranean Sea and the Black Sea) and an appropriate scope of relevant scientific expertise. Observers from the Regional Seas Conventions were also invited to each Task Group to help ensure the inclusion of relevant work by those Conventions. This is the report of Task Group 3 Commercially exploited fish and shellfish.JRC.DG.G.4-Maritime affair